If GFWL is installed as a separate application (found in Control Panel > Programs and Features), you are on the old save system.
C:\Users\[YourUserName]\Documents\Skidrow\50650\Storage\ resident+evil+6+save+game+location+non+steam
[Installation Drive]:\Resident Evil 6\save or ...\Resident Evil 6\players How to Identify the Correct File If GFWL is installed as a separate application
Most non-Steam installations store saves in the AppData folder associated with your Windows user profile. Path: %USERPROFILE%\AppData\Local\Capcom\Resident Evil 6\ Steam makes it easy, but non-Steam
If you’re playing Resident Evil 6 and it’s the Steam version — maybe an older retail DVD, a Windows Live title, or another digital release — finding the save folder can be a headache. Steam makes it easy, but non-Steam? Not so much.
The save game data is stored in a folder with a unique identifier, usually consisting of letters and numbers. Inside this folder, you'll find several files, including: